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1.
(2020高二上·白山期末)
工业上采用酸性高浓度含砷废水[砷主要以亚砷酸(
)形式存在]提取中药药剂
,工艺流程如下:
回答下列问题:
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(1)
已知砷元素与
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EN%3C%2Fmtext%3E%3C%2Fmath%3E)
同一主族,其原子比
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EN%3C%2Fmtext%3E%3C%2Fmath%3E)
原子多两个电子层,则砷元素在周期表中的位置为
,“沉砷”中与
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ENa%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmtext%3ES%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
反应的离子方程式为
。
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(2)
已知
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EAs%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmtext%3ES%3C%2Fmtext%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
与过量的
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsup%3E%3Cmtext%3ES%3C%2Fmtext%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
存在以下反应:
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EAs%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmtext%3ES%3C%2Fmtext%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmtext%3Es%3C%2Fmtext%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmn%3E3%3C%2Fmn%3E%3Cmsup%3E%3Cmtext%3ES%3C%2Fmtext%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmtext%3Eaq%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3Cmo%3E%E2%87%8C%3C%2Fmo%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmsubsup%3E%3Cmrow%3E%3Cmtext%3EAsS%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3Cmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3Cmo%3E%E2%88%92%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmsubsup%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
;“沉砷”中
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EFeSO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E4%3C%2Fmn%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
的作用是
。
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(3)
验证“焙烧”过程中生成的是
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EFe%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
的试剂是盐酸和
(写名称),写出对应反应的离子方程式:
。
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(4)
用稀硫酸调节
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmtext%3EpH%3C%2Fmtext%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmn%3E0%3C%2Fmn%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
,写出由
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ENa%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EAsO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E4%3C%2Fmn%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
制备
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EAs%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
发生反应的化学方程式:
。
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