1.
(2022高二下·安康期末)
硫化镉(
)难溶于水,常作颜料、油漆的添加剂。实验室以镉铁矿(主要成分是
、
、
及少量
和
)为原料制备高纯度
和绿色净水剂
的工艺流程如下:
![](//tikupic.21cnjy.com/2022/07/14/4b/cf/4bcfbe600d7ff63f0a226592d259f937_630x115.png)
已知如下信息:
①常温下,
,
可溶于水。
②此实验条件下,几种金属离子的氢氧化物沉淀pH如下:
金属离子 | 开始沉淀的pH | 完全沉淀的pH |
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EF%3C%2Fmtext%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3Ee%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E3%3C%2Fmtext%3E%3Cmtext%3E%2B%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
| 1.5 | 2.8 |
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EA%3C%2Fmtext%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3El%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E3%3C%2Fmtext%3E%3Cmtext%3E%2B%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
| 3.0 | 5.0 |
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EF%3C%2Fmtext%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3Ee%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E2%3C%2Fmtext%3E%3Cmtext%3E%2B%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
| 6.3 | 8.3 |
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EC%3C%2Fmtext%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3Ed%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E2%3C%2Fmtext%3E%3Cmtext%3E%2B%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
| 7.4 | 9.4 |
请回答下列问题:
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(3)
“沉镉”后滤液中
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3Ec%3C%2Fmtext%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3ES%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E2%3C%2Fmtext%3E%3Cmtext%3E-%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3Cmtext%3E%3D%3C%2Fmtext%3E%3Cmtext%3E1%3C%2Fmtext%3E%3Cmo%3E%C3%97%3C%2Fmo%3E%3Cmtext%3E1%3C%2Fmtext%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3E0%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E-%3C%2Fmtext%3E%3Cmtext%3E4%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3Cmtext%3Em%3C%2Fmtext%3E%3Cmtext%3Eo%3C%2Fmtext%3E%3Cmtext%3El%3C%2Fmtext%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3EL%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E-%3C%2Fmtext%3E%3Cmtext%3E1%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
时,
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3Ec%3C%2Fmtext%3E%3Cmrow%3E%3Cmo%3E%28%3C%2Fmo%3E%3Cmrow%3E%3Cmtext%3EC%3C%2Fmtext%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3Ed%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E2%3C%2Fmtext%3E%3Cmtext%3E%2B%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmrow%3E%3Cmo%3E%29%3C%2Fmo%3E%3C%2Fmrow%3E%3Cmtext%3E%3D%3C%2Fmtext%3E%3C%2Fmath%3E)
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3Em%3C%2Fmtext%3E%3Cmtext%3Eo%3C%2Fmtext%3E%3Cmtext%3El%3C%2Fmtext%3E%3Cmo%3E%E2%8B%85%3C%2Fmo%3E%3Cmsup%3E%3Cmrow%3E%3Cmtext%3EL%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E-%3C%2Fmtext%3E%3Cmtext%3E1%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsup%3E%3C%2Fmath%3E)
。若滤渣2为
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EA%3C%2Fmtext%3E%3Cmtext%3El%3C%2Fmtext%3E%3Cmtext%3E%28%3C%2Fmtext%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmtext%3EH%3C%2Fmtext%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3E%29%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E3%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmtext%3E%E3%80%81%3C%2Fmtext%3E%3Cmtext%3EF%3C%2Fmtext%3E%3Cmtext%3Ee%3C%2Fmtext%3E%3Cmtext%3E%28%3C%2Fmtext%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmtext%3EH%3C%2Fmtext%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3E%29%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E3%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3C%2Fmath%3E)
的混合物,则“调
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3Ep%3C%2Fmtext%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmath%3E)
”中需控制
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3Ep%3C%2Fmtext%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmath%3E)
的最小值为
。
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(4)
操作A包括过滤、洗涤、干燥等。验证
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EC%3C%2Fmtext%3E%3Cmtext%3Ed%3C%2Fmtext%3E%3Cmtext%3ES%3C%2Fmtext%3E%3C%2Fmath%3E)
沉淀是否洗净的操作是
。
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(5)
一种制备
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EK%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E2%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3Cmtext%3EF%3C%2Fmtext%3E%3Cmtext%3Ee%3C%2Fmtext%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3EO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmrow%3E%3Cmtext%3E4%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmsub%3E%3C%2Fmath%3E)
的方法是在一定条件下,以铁片为阳极,电解
![](//math.21cnjy.com/MathMLToImage?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmtext%3EK%3C%2Fmtext%3E%3Cmtext%3EO%3C%2Fmtext%3E%3Cmtext%3EH%3C%2Fmtext%3E%3C%2Fmath%3E)
溶液。写出电解时阳极的电极反应式
。
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